High capacity gas storage by a 4,8-connected metal-organic polyhedral framework.

نویسندگان

  • Chenrong Tan
  • Sihai Yang
  • Neil R Champness
  • Xiang Lin
  • Alexander J Blake
  • William Lewis
  • Martin Schröder
چکیده

The polyhedral complex [Cu(4)L(H(2)O)(4)]solv (NOTT-140) shows a 4,8-connected structure of rare scu topology comprising octahedral and cuboctahedral cages; desolvated NOTT-140a shows a total CO(2) uptake of 314.6 cm(3) (STP) cm(-3) at 20 bar, 293 K, and a total H(2) uptake of 6.0 wt% at 20 bar, 77 K.

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عنوان ژورنال:
  • Chemical communications

دوره 47 15  شماره 

صفحات  -

تاریخ انتشار 2011